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University of KansasCassini Studies |
DRAFT
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A.1 Collision Terms for Continuity Equations
The net source term for the continuity equation for species s can be expressed as Ss = Rs - Ls, where Rs is the primary plus chemical production rate and Ls is the chemical loss rate. The primary production rates (Rs0) were shown in Figure 2 for the three species. At higher altitudes these production rates are just proportional to the density of the relevant neutral species.
No chemical production is assumed for the light species, but chemical losses occur due to ion-neutral reactions with the medium and heavy mass neutrals and due to dissociative recombination with electrons. Denote the light, medium, and heavy ion species as L+, M+, and H+ and the neutrals as L, M, H. The light ion chemistry (and reaction rate coefficients) are:
| L+ + M ---> M+ + L | kLM | (A1) |
| L+ + H ---> H+ + L | kLH | (A2) |
| L+ + e ---> light neutrals | aL | (A3) |
Some more medium species chemistry is:
| M+ + M ---> H+ + L | kMM | (A4) |
| M+ + e ---> neutrals | aM | (A5) |
Some further heavy species chemistry is:
| H+ + e ---> neutrals | aH | (A6) |
The dissociative recombination rates were representative values from Keller et al. [1992]: as = as0 (300 / Te)1/2 with aL0 = 3.3 x 10-7 cm3 s-1, aH0 = 7 x 10-7 cm3 s-1, and aH0 = 6.4 x 10-7 cm3 s-1. The ion-neutral rate coefficients were chosen to improve the relative abundances of the ion species in comparison with Keller et al.: kLM = 2 x 10-10 cm3 s-1, kMM = 1 x 10-10 cm3 s-1, and kLH = 3 x 10-10 cm3 s-1.
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Tizby Hunt-Ward tizby@ku.edu |